C NMR (100 MHz, CD 3 OD) ?: 168.34 (s, C-7 VI ), 167.03 (s, C-7 I ), 12.0, 4.9 Hz, pp.547151-146 ,
42 (s, C-7 I ), 146.56 (s, C-4 I ), 146.39 (s, C-4 III ), 146.36 (s, C-4 II ), 140.68 (s, C-3,5 I ), 140.20 (s, C-3,5 II ), 139.99 (s, C-3,5 III ), 121.09 (s, C- 1 III )51 (s, C-1 II )00 (s, C-1 I ), 110.56 (d, C- 2,6 I ), 110.43 (d, C-2,6 III ) 1,2,6-Tri-O-galloyl-?-D-glucopyranose (3): Brown amorphous solid, H NMR (400 MHz, CD 3 OD) ?: 7.11 (2H, s, H-2,6 VI ), 7.05 (2H1H, dd, J = 12.1, 4.6 Hz, H-6b), pp.167-834535, 1979. ,
13 C NMR (100 MHz, CD 3 OD) ?: 168.19 (s, C-7 VI )74 (s, C-7 III ), 167.20 (s, C-7 II ), 166.34 (s, C-7 I ), 146.54 (s, C-4 VI ), 146.54 (s, C-4 I ), 146.38 (s, C-4 III ), 146.35 (s, C-4 II ), 140.75 (s, C-3,5 I ), 140.24 (s, C-3,5 II ), 140.03 (s, C-3,5 III ), 140.00 (s, C-3,5 VI ), 121.23 (s, C-1 VI ), 120.98 (s, C-1 III ), 120.41 (s, C-1 II ), 119.84 (s, C-1 I ), III ) II ), pp.4-7 ,
39 (1H, m, H-6b); 13 C NMR (100 MHz, CD 3 OD) ?: 167, 167.03 (C-7 II ), 166.93 (C-7 IV ) IV ), 146.39 (C-3 II ), 146.30 (C-3 III ), pp.4-52 ,
Brown amorphous solid MeOH); 1 H NMR (400 MHz, CD 3 OD) ?: ?-anomer (60%): 7.01 (2H, s, H-2,6 II ), 6.92 (2H, s, H-2,6 III ), 6.60 (1H, s, H-2 VI ), 6.49 (1H, s, H-2 IV ), 5.83 (1H, t, J = 10, 1H, dd, J = 12.7, 6.6 Hz, H-6), 5.12 (1H, t, J = 9.9 Hz1H, s, H-2 IV ), pp.496-502, 1932. ,
90 (1H, d, J = 13.0 Hz, H-6); 13 C NMR (100 MHz, CD 3 OD) ?: ? anomer: 169.78 (s, C-7 VI ), 169.32 (s, C-7 IV ), 167.94 (s, C-7 III ), 167.48 (s, C-7 II ), 146.41 (s, C-4 II ), 146.22 (s, C-4 III ), 145.94 (s, C-4 IV ), 145.87 (s, C-4 VI ), 144.82 (2×, s, C-5 IV and C-5 VI ), 140.16 (s, C-3,5 II ), 139.93 (s, C-3,5 III ), 137.62 (2×, s, C-3 IV and C-3 VI ), 126.36 (s, C-1 IV ), 125.96 (s, C-1 VI ) (s, C-1 III ) (s, C-1 II ), VI ), pp.35-40 ,
Brown amorphous solid MeOH); 1 H NMR (400 MHz, CD 3 OD) ?: 7.05 (2H, s, H-2,6 I ), III ), 6.61 (1H, s, H-2 VI ), 6.48 (1H, s, H-2 IV )1H, d, J = 8.3 Hz, p.955439 ,
13 C NMR (100 MHz, CD 3 OD) ?: 169.59 (s, C-7 VI ), 169.24 (s, C-7 IV )57 (s, C-7 III )92 (s, C-7 II ), 166.19 (s, C-7 I ), 146.62 (s, C-4 I ), 146.43 (s, C-4 II ), 146.27 (s, C-4 III )86 (s, C-4 IV ), 145.82 (s, C-4 VI ), 145.17 (s, C-5 IV ), 145.15 (s, C- 5 VI ), 140.82 (s, C-3,5 I ), 140.33 (s, C-3,5 II ), 140.11 (s, C- 3,5 III ), 137.80 (s, C-3 IV ), 137.78 (s, C-3 VI ), 126.24 (s, C-1 IV ), 126.24 (s, C-1 VI ), 120.45 (s, C-1 III ), 120.32 (s, C-1 II ) (s, C-1 I ), VI ), 116.69 (d, C-6 IV ) II ), 108.59 (d, C- 2 VI ), 108.21 (d, C-2 IV ), pp.4-43 ,
Brown amorphous solid, H NMR (400 MHz, CD 3 OD) ?: 7.05 (2H, s, pp.4-27 ,
13 C NMR (100 MHz, CD 3 OD) ?: 168.58 (s, C-7), 146.50 (s, C-3,5), 139.71 (s, C-4), 121.77 (s, C-1) Caffeic acid (9): White amorphous solid, H NMR (400 MHz, CD 3 OD) ?: 7.59 (1H, d, J = 15.9 Hz, pp.0-61 ,
9 Hz, H-8); 13 C NMR (100 MHz, CD 3 OD) ?: 169.05 (s, C-9), p.77306576522088 ,
Yellow amorphous solid, MeOH, vol.10 ,
H-5?); 13 C NMR (100 MHz, CD 3 OD) ?: 179.53 (s, C-4), 166.21 (s, C-7), 163.11 (s, C-5) Isoquercetin Yellow amorphous solid, ), 3.20 (1H, ddd, J = 9.7, 5.5, 2.3 Hz 132.31 (d, C-2?,6?), pp.69-72 ,
Brown amorphous solid; 1 H NMR (400 MHz, CD 3 OD) ?: 7, 1H, m, H-6?)1H, br s, p.8539785039, 1920. ,
13 C NMR (100 MHz, CD 3 OD) ?: 166, 163.1 (C-5), 159.8 (C-2) 123.1 (C-1?), pp.75-78 ,
50 (2H, m, H-5?); 13 C NMR (100 MHz, CD 3 OD) ?: 180.02 (s, C (s, C-3), 123.13 (s, C-1?), ), 3.92 (1H, dd, J = 5.2, 2.9 Hz, H-3?), 3.86 (1H, m 159.38 (s, C-2), 158.62 (s, C-9), 149.90 (s, C-4?), pp.9140-9146 ,
86 (1H, br d, J = 12.2 Hz, 12.2, 5.7 Hz, H-6?b), 3.43 (1H, m, H- 5?), 3.39 (1H, m, pp.5938-5942 ,
10 (3H, s, H-12), 1.01 (3H, s, H-11); 13 C NMR (100 MHz, CD 3 OD) ?: 202, p.17 ,
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